The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions
Submitted by Jun Zhu on Fri, 08/15/2014 - 23:44
Authors:
Liu Liu, Jun Zhu and Yufen Zhao
Journal:
Chem. Commun.
Year:
2014
Volume:
50
FirstPage-LastPage:
11347 - 11349
TOC:
Abstract:
Density functional theory (DFT) calculations were carried out to investigate the [2+2], [3+2] and [4+2] cycloadditions of the phosphaethynolate anion (PCO−). The results reveal that the electronic properties of different unsaturated compounds play a crucial role in reactivity and regioselectivity.
http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC04610B#!divAbstract
Doi:
10.1039/C4CC04610B