[Bi6Mo3(CO)9]4−: a multiple local σ-aromatic cluster containing a distorted Bi6 triangular prism
Submitted by Jun Zhu on Fri, 03/19/2021 - 08:43
Authors:
Lei Qiao, Dandan Chen, Jun Zhu, Alvaro Muñoz-Castroc and Zhong-Ming Sun
Journal:
Chem. Commun.
Year:
2021
TOC:
Abstract:
The first Zintl cluster containing a distorted Bi6 triangular prism, [Bi6Mo3(CO)9]4−, has been synthesized and structurally characterized. Quantum chemical calculations indicated that the distorted cage cluster features multiple local σ-aromaticity.
https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC00734C#!divAbstract
Doi:
10.1039/D1CC00734C